Search results for " layered"

Ni/Zn Layered Double Hydroxide (LDH) Micro/Nanosystems and Their Azorubine Adsorption Performance

2021

A membranous shaped Ni/Zn layered double hydroxide based nanohybrid was obtained using a low-cost template-free hydrothermal process at optimized growth conditions of 180 °C for 6 h. The synthesized nanohybrid was structurally, texturally and morphologically characterized using different techniques such as X-ray diffraction, FTIR, XPS spectroscopy, BET analysis and FESEM microscopy. The adsorption performance of our product was estimated through the Azorubine dye removal from synthetic wastewater. We therefore studied the synergic effects of Ni/Zn adsorbent dosage, contact time, pH, adsorbate concentration, stirring speed and temperature on the Azorubine adsorption efficiency. In this inves…

Emerging switchable ultraviolet photoluminescence in dehydrated Zn/Al layered double hydroxide nanoplatelets

2019

AbstractLayered double hydroxides show intriguing physical and chemical properties arising by their intrinsic self-assembled stacking of molecular-thick 2D nanosheets, enhanced active surface area, hosting of guest species by intercalation and anion exchanging capabilities. Here, we report on the unprecedented emerging intense ultraviolet photoluminescence in Zn/Al layered double hydroxide high-aspect-ratio nanoplatelets, which we discovered to be fully activated by drying under vacuum condition and thermal desorption as well. Photoluminescence and its quenching were reproducibly switched by a dehydration–hydration process. Photoluminescence properties were comprehensively evaluated, such a…

Heat Conduction Problem for Double-Layered Ball

2014

Heat conduction models for double layered spherical sample are developed. Parabolic (classic, based on Fourier’s Law) and hyperbolic (based on Modified Fourier’s Law) heat conduction equations are used to describe processes in the sample during Intensive Quenching. Solution and numerical results are obtained for 1D model using Conservative Averaging method and transforming the original problem for a sphere to a new problem for a slab, with non classic boundary condition. Models include boundary conditions of third kind and non-linear BC case. Numerical results are presented for several relaxation time and initial heat flux values.

Self-Assembly of 1D/2D Hybrid Nanostructures Consisting of a Cd(II) Coordination Polymer and NiAl-Layered Double Hydroxides

2015

The preparation and characterization of a novel hybrid material based on the combination of a 2D-layered double hydroxide (LDH) nanosheets and a 1D-coordination polymer (1D-CP) has been achieved through a simple mixture of suspensions of both building blocks via an exfoliation/restacking approach. The hybrid material has been thoroughly characterized demonstrating that the 1D-CP moieties are intercalated as well as adsorbed on the surface of the LDH, giving rise to a layered assembly with the coexistence of the functionalities of their initial constituents. This hybrid represents the first example of the assembly of 1D/2D nanomaterials combining LDH with CP and opens the door for a plethora…

On the moving loads problem in discontinuous homogeneous beams and layered beams with interlayer slip

This manuscript contains the main part of my research performed in this last triennium at the Department of Civil, Environmental, Aerospace and Materials Engineering, University of Palermo, and at the Department of Basic Sciences in Engineering Sciences (Unit of Applied Mechanics), University of Innsbruck, Austria. The research adheres to a common procedure of solving a scientistic problem. That is, introduction to the problem, selection of the mathematical and physical tools to model the problem, proposed solution, and numerical validation. The thesis proposes a novel modal superposition approach to the moving loads problem on discontinuous homogeneous beam and layered beam with interlayer…

Influence of antioxidants intercalated layered double hydroxides (AO-LDHs) on the thermo-oxidative stability of pla and pe based nanocomposites

2016

Layered double hydroxides (LDHs) are excellent host matrices for storage and delivery of antioxidants (AOs).

Mechanical behavior of polylactic acid/polycaprolactone porous layered functional composites

2016

Abstract Biopolymeric porous devices exhibiting graded properties can play a crucial role in several fields, such as tissue engineering or controlled drugs release. In this context, the gradient of a specific property can be achieved by developing porous laminates composed by different types of materials. This work presents for the first time a multi-phasic porous laminate based on polycaprolactone (PCL) and polylactic acid (PLA) prepared by combining melt mixing, compression molding and particle leaching. All the materials were characterized from a morphological and a mechanical point of view. The results put into evidence the possibility to tune and to predict the mechanical properties by…

Structural Characterisation of Complex Layered Double Hydroxides and TGA-GC-MS Study on Thermal Response and Carbonate Contamination in Nitrate- and …

2015

Layered double hydroxides (LDHs) are versatile materials used for intercalating bioactive molecules in the fields of pharmaceuticals, nutraceuticals and cosmetics, with the purpose of protecting them from degradation, enhancing their water solubility to increase bioavailability and improving their pharmacokinetic properties and formulation stability. Moreover, LDHs are used in various technological applications to improve stability and processability. The crystal chemistry of hydrotalcite-like compounds was investigated by X-ray powder diffraction (XRPD), automated electron diffraction tomography (ADT) and thermogravimetric analysis (TGA)-GC-MS to shed light on the mechanisms involved in io…

Thickness-dependent properties of ultrathin bismuth and antimony chalcogenide films formed by physical vapor deposition and their application in ther…

2021

This work was supported by the European Regional Development Fund (ERDF) project No 1.1.1.1/16/A/257. J. A. acknowledges the ERDF project No. 1.1.1.2/1/16/037. Institute of Solid State Physics, University of Latvia, Latvia as the Center of Excellence has received funding from the European Union's Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017 TeamingPhase2 under grant agreement No. 739508, project CAMART2 . The raw/processed data required to reproduce these findings cannot be shared at this time as the data also form a part of an ongoing study.

MZ-35, a new layered pentasil borosilicate synthesized in the presence of large alkali cations

2013

Abstract A new layered borosilicate has been synthesized in the presence of cesium and sodium cations and its structure has been solved by a combination of automated diffraction tomography (ADT) and X-ray powder diffraction (XRPD). MZ-35 has a composition NaCs 2 [BSi 7 O 16 (OH) 2 ](OH) 2 ·4H 2 O and features space group P-4m2. The unusually small unit cell ( a 7.3081 A, c 10.7520 A) is shared by two random-stacked configurations of the structure: a network of connected pentasil units related to the layer of RUB-18 and a bidimensional checkerboard of intersecting ladders of 4-membered rings. The two configurations are related by the simple face-sharing inversion of a hydroxyl-bearing tetrah…